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Bohr had... discovered that the frequencies corresponding to very large integers could be calculated accurately from the classical mechanics; they were simply the number of times that an ordinary electron would complete the circuit of its orbit in one second when it was at a very great distance from the nucleus of the atom to which it belonged. This could only mean that when an electron receded to a great distance from the nucleus of its atom, it not only assumed the properties of an ordinary electron, but also behaved as directed by the classical mechanics. Yet the classical mechanics failed completely for the calculation of frequencies corresponding to small orbits.

 

James Jeans

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In the interior of the atom, Bohr had tried the plan of retaining the particle-electron and modifying the classical mechanics. Heisenberg took the opposite course, his procedure amounting in effect to retaining the classical mechanics, at least in form, and modifying the electron. Actually, the electron dropped out all together, because it exists only as a matter of inference and not of direct observation. For the same reason, the new theory contains no mention of atoms, nuclei, protons, or of electricity in any shape or form. The existences of all these are matters of inference, and Heisenberg's purely mathematical theory could no more make contact with them than with the efficiency of a turbine or with the price of wheat.

 

James Jeans

 

This fallacious result is not... a peculiarity of classical mechanics; it is given also by a very wide class of possible systems of mechanics. This being so, no minor modification of the classical mechanics can possibly put things right. Something far more drastic is needed; we are called upon to surrender either the continuity or the causality of classical mechanics, or else the possibility of representing changes by motions in time and space.

 

James Jeans

 

Precisely similar ideas are applicable to the molecules that form the air in a room. ...The classical mechanics now predicts that the whole energy of motion will be changed into radiation [heat], so that the molecules will shortly be found lying at rest on the floor... In actual fact they continue to move with undiminished energy, forming a perpetual-motion machine in defiance of classical mechanics. ...We have passed from one to another of three worlds... from the man-sized world to the world of the electron.

 

James Jeans

 

This spectrum is of the type known in spectroscopy as a line-spectrum. Its appearance is that of a group of bright lines on a dark background, indicating that the radiation divides itself between a number of clearly defined frequencies, and that there is no radiation in between. Before Bohr's explanation appeared, these frequencies had been supposed to belong to some sort of vibration taking place in the hydrogen atom - like frequencies of the musical note which is heard when a bell or piano wire is made to vibrate. It now became clear that they had an entirely different origin. The energy exhibited in the spectrum was not liberated by a vibration, or any kind of continuous motion, but by the sudden jump of an electron to an orbit of lower energy, and its frequency was determined by the compulsion put upon it to form a single quantum.

 

James Jeans

 

Heisenberg's name will always be associated with his theory of quantum mechanics, published in 1925, when he was only 23 years old. For this theory and the applications of it which resulted especially in the discovery of allotropic forms of hydrogen, Heisenberg was awarded the Nobel Prize for Physics for 1932.
His new theory was based only on what can be observed, that is to say, on the radiation emitted by the atom. We cannot, he said, always assign to an electron a position in space at a given time, nor follow it in its orbit, so that we cannot assume that the planetary orbits postulated by Niels Bohr actually exist. Mechanical quantities, such as position, velocity, etc. should be represented, not by ordinary numbers, but by abstract mathematical structures called "matrices" and he formulated his new theory in terms of matrix equations.

 

Werner Heisenberg